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nieuwland j vogt r chemistry acetylene 1945

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Textbook in PDF format In this work an attempt is made to present a brief but fairly complete account of the preparation, properties and reactions of acetylene along with an extensive classified bibliography. A restricted section of this subject, namely the manufacture of calcium carbide and the derived acetylene, is covered quite thoroughly in a number of earlier books and in several special periodicals. Accordingly, only an abridged discussion of this topic appears here. The use of acetylene as a raw material for industrial syntheses also has been the subject of a few books and numerous short review articles. The arrangement of this work is based entirely on a classification of the methods of preparation and type reactions of acetylene, rather than on considerations of historical sequence or industrial status. In any treatise on acetylene numerous references to other acetylenic compounds are inevitable. In the first place many of these are best prepared by substitution in acetylene. The substitution products in turn serve as intermediates in many useful laboratory preparations; accordingly, a short section has been included which points out the principal stepwise syntheses from acetylene through substituted acetilenes. Secondly, many reactions of acetylene are best understood by comparison with parallel reactions of other acetylenic compounds. Historically, a number of reactions were first applied to other acetylenic hydrocarbons and were later adapted to acetylene, and this order of development is still common, because reactions of acetylene are often more complicated and difficult than those of other compounds of the series. For these reasons numerous reactions of other acetylenic compounds are cited, but it should be remembered that a complete survey of the reactions of the series is not intended. Because of unavoidable delays in the completion and publication of this work, it has not been possible to cover the literature on most topics later than 1938

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Nieuwland J., Vogt R. The Chemistry of Acetylene 1945.pdf 22.9 MB

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nieuwland j vogt r chemistry acetylene 1945