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tezuka y topological polymer chemistry concepts pract 2022

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Textbook in PDF format This book provides a comprehensive description of topological polymers, an emerging research area in polymer science and polymer materials engineering. The precision polymer topology designing is critical to realizing the unique polymer properties and functions leading to their eventual applications. The prominent contributors are led by Principal Editor Yasuyuki Tezuka and Co-Editor Tetsuo Deguchi. Important ongoing achievements and anticipated breakthroughs in topological polymers are presented with an emphasis on the spectacular diversification of polymer constructions. The book serves readers collectively to acquire comprehensive insights over exciting innovations ongoing in topological polymer chemistry, encompassing topological geometry analysis, classification, physical characterization by simulation and the eventual chemical syntheses, with the supplementary focus on the polymer folding, invoked with the ongoing breakthrough of the precision AI prediction of protein folding. The current revolutionary developments in synthetic approaches specifically for single cyclic (ring) polymers and the topology-directed properties/functions uncovered thereby are outlined as a showcase example. This book is especially beneficial to academic personnel in universities and to researchers working in relevant institutions and companies. Although the level of the book is advanced, it can serve as a good reference book for graduate students and postdocs as a source of valuable knowledge of cutting-edge topics and progress in polymer chemistry. Introductory Remarks Graph Theoretical and Knot Theoretical Analyses of Multi-cyclic Polymers Classification, Notation and Isomerism of Topological Polymers Exact Evaluation of the Mean Square Radius of Gyration for Gaussian Topological Polymer Chains Fundamentals of the Theory of Chromatography of Topologically Constrained Random Walk Polymers Construction of Multicyclic Polymer Topologies through Electrostatic Self-assembly and Covalent Fixation (ESA-CF) Topological Analysis of Folded Linear Molecular Chains Cyclotides—Cyclic and Disulfide-Knotted Polypeptides Construction of a Macromolecular K3,3 Graph Topology by the ESA-CF Polymer Folding Programmed Polymer Folding Spatially and Chemically Programmed Polymer Folding by the ESA-CF Protocol Macromolecular Rotaxanes, Catenanes and Knots Recent Progress on the Synthesis of Cyclic Polymers Recent Progress on the Synthesis of Cyclic Polymers via Ring-Closure Methods Ring-Expansion Polymerization of Cycloalkenes and Linear Alkynes by Transition Metal Catalysts Synthesis of Cyclic Vinyl Polymers via N-Heterocyclic Carbene (NHC)-Initiated Anionic Polymerization and Subsequent Ring-Closure Without Highly Dilute Conditions Controlled Ring-Expansion Polymerization Based on Acyl-Transfer Polymerization of Thiiranes with Aromatic Heterocycles as Initiators A Conjunctive RC and RE Polymer Cyclization with Zwitterionic Telechelic Precursors Cyclic Polymers Synthesized by Spontaneous Selective Cyclization Approaches Unstoichiometric Polycondensation for the Synthesis of Aromatic Cyclic Polymers Entanglement in Solution of Non-concatenated Rings Dilute Solution Properties of Ring Polymers Cyclic Polymers for Innovative Functional Materials Surface Functionalization with Cyclic Polymers Morphological Significances of Cyclic Polymers in Solution and Solid State Transforming Cyclic/Linear Polymer Topologies: Emerging Techniques and Opportunities

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Tezuka Y. Topological Polymer Chemistry. Concepts and Pract.2022.pdf 8.0 MB

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tezuka y topological polymer chemistry concepts pract 2022

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