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philippi p thermodynamics from fundamentals multiphase systems 2024

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Textbook in PDF format Foreword Preface List of Figures List of Tables The Principles of Thermodynamics The First Principle The Laws of Gases Pressure Temperature From Stahl to Lavoisier Gay-Lussac and Clapeyron The Steam Engines and Carnot The Principle of Energy Conservation Joseph Black Joule's Experiments Exercise The Principle of Energy Conservation The Joule Expansion Specific or Molar Heats Ideal Gases Equilibrium and Non-equilibrium States The Second Principle Reversible and Irreversible Processes An Abrupt Isothermal Expansion Expansion Work Quasi-static Isothermal Expansion Inverse Process The Cycle Exercises Work and Heat Conversion The Role of Dissipation Exercises The Second Principle of Thermodynamics Statements of the Second Principle Exercises Sadi Carnot and Émile Clapeyron Thermodynamic Scale of Temperature Using the Ideal Gas Properties for Calculating the Conversion Efficiency for the Carnot's Cycle Exercises Reversible Cycles Other Than Carnot's Cycle Exercises Clausius Inequality and Entropy External and Internal Sources of Entropy Exercises The Meaning of Entropy Thermodynamic Equilibrium The Equilibrium State Introduction Open Systems and Gibbs Potential Intensive and Extensive Variables Homogeneity of the Equilibrium State Exercises Legendre Transforms of the Internal Energy Helmholtz Energy Enthalpy Gibbs Energy Exercises Maxwell Relations The Entropy as a Function of the Temperature and Volume The Internal Energy as a Function of the Temperature and Volume Exercises Minimum Principles Minimum Principle for the Internal Energy Minimum Principle for Enthalpy Minimum Principle for the Helmholtz Energy Exercises Phase Equilibrium Andrews, van der Waals and Maxwell Exercise Gibbs Potential to Find the Transition Pressure Maxwell Area Rule Exercise The Transition State Exercise The Liquid-Vapor Phase Diagram Clausius-Clapeyron Equation Exercise The Law of Corresponding States Acentric Factor Exercises Some Popular Cubic Equations of State Redlich-Kwong Soave Peng-Robinson Exercises The Virial Equation of State Second Virial Coefficient Third Virial Coefficient Exercises Calculation of State Variables Exercises Non-ideal Mixtures Partial Volumes and the Amagat's Law Exercise Gibbs–Duhem Equation for Mixtures Ideal Gases Exercises The Lewis Concept of Fugacity Calculation of the Fugacity Coefficient for a Virial Equation of State Calculation of the Fugacity Coefficient for a Cubic Equation of State Exercises Ideal Solutions Raoult's Law Exercise Non-ideal Solutions Gibbs Energy in Excess Margules Model Exercises Activity Coefficients from Molecular Groups Combinatorial Activity Coefficient Residual Activity Coefficient Exercises Phase Equilibrium Phase Equilibrium at Low Pressures Phase-Equilibrium Using the Virial Equation of State for the Vapor Phase Phase Equilibrium Using a Cubic Equation of State for the Vapor Phase Summary Surface Physics Introduction Laplace Exercises The Form of a Sessile Drop Surface Tension and the Helmholtz Energy Exercise A Deeper Insight into the Physics of Interfaces Exercises Density Profile Interface Thickness Surface Tension Sample Case: Water Exercise Interaction Between Fluids and Solid Surfaces Exercise Dynamic Contact Angle Surface Energies: Cahn's Theory Hydrophilic Surfaces Hydrophobic Surfaces Contact Angle and Adhesion Energy Exercise Emulsions Introduction to Non-equilibrium Thermodynamics Non-equilibrium States Introduction The Local Approach Mass Conservation Exercises Momentum Balance Equation Exercises Energy Conservation The Heated Cavity Problem The Law of Increasing Entropy Exercises Multiphase Systems Introduction The Singular Interface Approach Mass Conservation Momentum Balance Equation Particular Cases Exercises Numerical Methods for the Singular Interface Approach The Diffuse Interface Approach Surface Forces Momentum Balance Equation Summary Exercise Internal Energy Balance Equation Numerical Methods for the Diffuse Interface Approach Multicomponent Systems Introduction Mixtures Without Segregation Effects Transport Equations Exercises Segregation Effects in Non-ideal Mixtures Pressure Tensor and the Equation of State Interface Physics Spinodal Decomposition in Multicomponent Systems Non-equilibrium Thermodynamics from a Kinetic Standpoint Scales of Investigation The Boltzmann Equation The Liouville Equation The Long-Range Term Mean Field Theory The Short-Range Collision Term Elementary Properties of the Collision Term The H-Theorem Macroscopic Transport Equations Exercises Kinetic Models for the Collision Term The BGK Collision Model Beyond BGK The Stokes Hypothesis Exercises Non-ideal Fluids Two Phase Liquid-Vapor Systems Exercises Multicomponent Systems Macroscopic Equations Using a Reverse Standpoint to Find the Microscopic Parameters and the Intermolecular Force Exercises Appendix The Euler–Lagrange Equations References

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Philippi P. Thermodynamics. From Fundamentals to Multiphase...Systems 2024.pdf 10.2 MB

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philippi p thermodynamics from fundamentals multiphase systems 2024