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szostak m amide bond activation concepts reactions 2023

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Textbook in PDF format This book provides the reader with insight into the advances that have taken place in the field of amide bond activation. It focuses on both the fundamental structural properties of the amide bond and the synthetic reactions mediated by transition-metals. By discussing amide bond activation in terms of modern organic synthesis, the reader is provided with a thorough overview of the area and its crucial role in forging carbon-carbon and carbon-heteroatom bonds. Sample topics discussed within the work include: Cross-coupling of amides Amide bond activation by twisting and nitrogen pyramidalization Electrophilic amide bond functionalization Transition metal-catalyzed radical reactions of amides Amide bond esterification, hydrolysis and transamidation Classical bridged lactams and anomeric amides Computational studies of amide C-N bond activation Cross-coupling of esters by C-O activation The book is immensely valuable to synthetic chemists in academia and the pharmaceutical industry who wish to gain an in-depth understanding of the concept of amide bond activation. Bridged Lactams as Model Systems for Amidic Distortion Modification of Amidic Resonance Through Heteroatom Substitution at Nitrogen: Anomeric Amides Amide Bond Activation by Twisting and Nitrogen Pyramidalization Transition-Metal-Free Reactions of Amides by Tetrahedral Intermediates Electrophilic Amide Bond Functionalization Transamidation of Carboxamides and Amide Derivatives: Mechanistic Insights, Concepts, and Reactions Amide Bond Esterification and Hydrolysis Activation of Amide C–N Bonds by Nickel Catalysis Pd–NHC Catalysis in Cross-Coupling of Amides Cross-Coupling of Amides Through Decarbonylation Transition Metal-Catalyzed Radical Reactions of Amides Weinreb Amide as a Multifaceted Directing Group in C–H Activation Computational Studies of Amide C–N Bond Activation Esters as Viable Acyl Cross-Coupling Electrophiles Cross-Coupling of Aromatic Esters by Decarbonylation

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Szostak M. Amide Bond Activation. Concepts and Reactions 2023.pdf 8.6 MB

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szostak m amide bond activation concepts reactions 2023